play doh elmo color mixer etarigan Thursday, January 12, 2017


please give a warm welcome to dr. hu. [applause] thank you, carol lynn. i have to say that i am so delighted tobe here because this is one of my favorite museums in the whole world. and i'm glad you're here too. so what i'm showing you here these are different colors. and the there's nothing nano lookingabout them. but in fact, their color comes from their nanoscale properties. these are solutions of quantum dots.

i'm going to talk about different kinds of quantum dots. but t's a new way of making color. by shaping materials and sizes at the nanoscale. and to your left i have a couple ofstructures that my group makes. and they look weird and they are trulyat the nanoscale. so, that's truth in advertising. and as yousee most if it looks great. this is what it's supposed to look like when it lights up. but to talk a little bit more about what we do in my group we make boxes for emitters at the nanoscale.

and these are three of the boxes that we make. we make something called a microdisk, we make a nano-ladder with holes in it and here is adimension of a hundred nanometers, we make something called a photonics crystal and you can also see the size scale here, 500 nanometers. we make these very tiny structures in an environment like this, it's called a cleanroom, you have to dress up like that becausethe little nano-boxes that you make are so small that if a piece of skinflakes off or a piece of dust

or whatever flakes off on the device it could kill the entire device. and then wemeasure our structures in labs like this. lots and lots of instrumentation. so, a lot of big lab equipment to try and seesomething like color at the nanoscale. and this is casey russell and who are two of the peoplein my group making those measurements. but i just want to set the scale for everyone. something that we all know about, thediameter of a human hair.

does anybody know the size of a human hair? do i have a guess? say it louder? 600 nanometers? oh, close. [millimeter?] millimeter? yeah, 500 did you say? okay. all good guesses. the diameter of a typical human hair,although it varies because we all very, is about 70 micrometers, 70 microns, thats less than a millimeter, but it's about 70,000 nanometers.

so, it's almost a 100,000 times wider in it's thickness than a nanometer. now, we're not going to today work at the nanometer, but there is an importance inunderstanding the nanometer for light. but first before we go to what is nanometer about light, let's think about where does color come from? you could ask does it come from nature? like we get flowers, beautiful flowersand we grind them up and maybe we can get color out of them.

or lot of things in nature have anatural color like this butterfly. or maybe it's from the light? actually without the light would there be any color? or could we see any color?so light's pretty important too. or maybe it's from our eyes. our eyes have to do something, have to, you know be in this loop somehow. and of course the answer is it's from the interaction of all of them. and it has to be exactly the right interaction. so how do i know this? could you distribute the goggles?

so color has to have the input of all of it. it has to be the material you're looking at, and if it has a nanostructure or not, and it has to be the light and what kindof light you're using to look at it, and of course it has to go into your eye, and your eye has its own way of filtering light. so, how do we know it's true? we're passing around some goggles. put them on, take a look and tell me what do you see? is there anything weird?

someone said "oo". you've done this before. so i hit theanswer, it's splitting the light. okay, what you should see is you look around and suddenly you see rainbows everywhere.these are not ordinary goggles. they look transparent, they look likemaybe the kinds of glasses you're used to wearing. but in fact they have a pattern of tiny lines etched into the lens. and those patterns of tiny lines are called gratings. and those gratings have distances line to line

they're etched into the plastic that's your lens and those gratings are spaced on the order of a few 100 to a few 1,000 nanometers apart. so the message from this is something special happens when you have something at the nanometer scale. in the material that you are looking at, but there's a reason why something special happens at that particular dimension. because if we ask, what is nanoscale about the light? light is part of the family of the electromagnetic spectrum. electromagnetic waves transportedthrough the air or through anything

you know radio and television, so, that's part of the electromagneticspectrum that you use all the time. you may know x-rays when you go to the doctor, you know uvrays and you know toavoid them. but a very small sliver of that broad electromagneticspectrum is visible light, which we respond to. there are other parts of the electromagnetic spectrum we respond to, but, visible light has wavelengths from between 400 to 700 nanometers

so, how do we utilize this fact? we already know that something magic happens when you match light to something that has a natural nanostructure. so what do we do in my group? we make our own colors by making what are called quantum dots in quantum wells. here's an example of a quantum dot. these quantum dots are about 30 nanometers wide and five nanometers high, about a hundred thousand times less than a human hair.

so it's very small. and i want to tell you how making quantum dots in a material can dramatically change it. so this is a piece of material, you can see right through it. are there any guesses about what this material is? [plastic?] plastic? glass? this is a material called gallium nitride.

you can see right through it, so the question is, duh, what's, where's the color? but i'll tell you, and i'm going to show you later, that this material, this material is at the heart of this flashlight. that gives you blue light. and it doesn't only give you blue light. i'm going to show you later, it gives you,as you change it subtly, it gives you any color that you want. and, so, how do we do that?

we take that material, that seemstransparent, that seems to have no color at all, and what we do is shape little lightemitters in the material that have dimensions on the order of ten, a few nanometers. then we place these little light emitters into what i call a perfectly matched nanostructure. we put them in their own environment. and what does that environment do? and so here are examples of the environment that you've seen before. we call this a microdisk, we call this a photonic crystal. and that right environment, what makes it perfect?

the perfection means that we have madethat little environment, that little box for the light emitters, to be resonant, to be exactly the right size for the wavelength of the light emitters in the box. so, these quantum dots give out light at a certain wavelength. and then we put those quantum dots into a structure where the structurehas exactly the same wavelength. a structure that is made uniquly for those little light emitters, and therefore adapts to the tones of the nanostructure. and what's the result? why is it good to match?

well, we get just like when you have a flute, and you have a really well made musical instrument and you just play it exactly right, your breath is exactly right and the acoustic wave that you generate is exactly right for that instrument you get a beautiful tone. you do the same thing optically, you get something called resonance. when you match the wavelength of the color of the nanoparticle that you make to the wavelength response of the little box that you make. so you make actually beautiful music. only you make beautiful music optically.

and you get true colors just like you get true pitch, true frequency, that beautiful sound when everything is matched just right. you get control of the color emission. so, what that means is by making the right box and by controlling that box you can actually make photons, make the light, go out when you want to not when it wants to. and that control is pretty amazing. and then, because of that match these devices are more energy-efficient. and what i mean by that

we're going from playing with color at the nanoscale to using color at the nanoscale and using some of these techniques. we get super efficient light emission because we can match. so for example we've made lasers using those quantum dots in a photonic crystal structure with ahundred nanaowatts power threshold. now, nano wavelength, nanoscale wavelength, nanoscale energy, watts is power, it's energy per unit time. just to give you an idea is, i mean, nano-anything sounds amazing, but how amazing is it?

so, i've been using a laser pointer, and there's a laser pointer here on thescreen. so, does anybody have a guess about how much power, like in watts, i need for this laser pointer to generate light? actually it generates light on me betterthan it does on the screen. are there any guesses? yeah - 300 watts. [microwatts] microwatts. i have 300 watts; i have 5 microwatts. in the back, you can yell out because there's a lot of noise.

50 watts, ok anything else? yeah, 30, did you say 30? okay 30, 50, um, 305 microwatts. so, one thing to do is to look at what powers are laser pointers. and this is anotherlaser pointer, believe me it's typical, and it's run by two one and a half volt batteries. okay, so that's three volts.

and it has a current of about a milliamp, one one thousandth of an amp. so, if i use that i can do a calculation because power is current times voltage. and if you haven't learned that yet you will learn that soon. so, power is current times voltage. i have milliamps, a thousandth of an amp times a volt, so, that means this laser will take a few milliwatts of power, a few to maybe ten milliwatts of power. so, our nano-laser has about 10,000 times less power.

a milliwatt compared to a hundred nanowatts. now, i'm not being entirely truthful in the way that we can use them today, but the important thing is the possibility. okay let's go further. it's not only lasers, but we have devices called light emitting diodes, led's. this is a light emitting diode.it doesn't look nano, but the heart of its operation is nano. these are also flashlights made of light emitting diodes.

this is white. this is blue. here, this is made up of light-emitting diodes and if i turn this on okay, i can get green, i can get red, blue, i can mix red, green and blue getorange, different colors of blue, purple, yellow. so this is a more powerful light emitting diode that has multiple colors and by adding those multiple colors ican make any color.

and basically if i mix all colors doessomebody know what i can get? yes. [white] white, okay. so, what i'm showing here is some work we did. there's still nanostructures it's made out of gallium nitride, which look completely transparent and when we touch an electrical signal to one of these little micro disks we see it light up. so, this is an example of a possibility for new kind of lighting. as you could see maybe from here. it's a new kind of lighting.

and why is that important? it's important because all the electricity we use today all the electricity that's consumed allover the world an amazing 20 percent, one-fifth of all the expenditure of electricity that weuse is used for lighting, just so that youcan stay up late and study, or you can read a book or whatever elseyou need to use light for. and this is a composite image. it shows you, obviously it's not nightall the time in the world at the same time, but this is a composite image,

so its taken over the entire 24 hours. the bright spots show you where people are using light. and so, we need to get electricity from somewhere and twenty percent of the electricity isused for lighting. a typical large electric power plantgenerates one hundred megawatts of power. that means a hundred million watts. so, again, watts is power, that's energy per unit time and then you integrate over time and you get something like watt hours

or kilowatt hours and that's thetotal energy use. so, here's a prediction, by 2027 leds for lighting could save 348 terawatt hours of energy. does anybody know what tera means? yeah. thousand? more than a thousand, much more than a thousand. yes. you said? 400,000? it's a trillion watt hours. so thinkabout that, it's hard to imagine.

if we go back, i'm coming to this ina minute, if you go back to a light bulb, if any of you have light bulbs, you think about a 100 watt light bulb, a100 watts, and you keep this light bulb running all day, that's a hundred times 24, 2400 watt hours. but think about 350 trillion watt hours. it's pretty much. and to put it in other terms those are44 electric power plants, and it's $30 billion dollars by today's prices.

so, imagine, imagine the savings we would have in the use of our electricity. imagine whatwe could use that power for in other terms. and imagine all the things like co2 generation and climate warming thatwe could avoid if we were to go to a more natural kind of lighting scheme. why do i say natural? so today, i'm sure, i don't know how many, how many of you still have light bulbs? a few of you, ok, so, this light build, you can sort of see the structure, you can see the structure here.

this light bulb gives light, but what its best at doing is giving off heat. so, what you do is you run electrons through the wires of that light bulb and you make it really really hard for them to get through. you give them a lot of resistance andthey get so tired they're generating heat and generating heat and finally they get red hot. and then we get light. but really we got light at the end of a story that gave us heat. then,

how many you have this at home? okay, good, compact fluorescent lighting. this is a way to generate light that'sslightly more efficient, but there are issues with this too like there is mercury in this lamp and it's really hard to recycle this. and then we have led light bulbs that look like that, that look like this, that you could buy at home depot except the problem is they're a little bit more expensive.

and part of the reason for doingthe research we do is trying to make these kinds of light bulbs even more efficient but less expensive. that's basically it. it's an introductionto a little bit of what my group does. and i have to say that we think the nano-future's so bright wegotta wear shades, and i want to say also that when i talk about playing with lightit's more fun to play with others these are my groups at santa barbara

and now at harvard and there are manymore people over the years who supported some of the stuff that i showed you today. also it's good to have the funds tobe able to do this kind of research so we're very grateful to funding agencies like thedepartment of energy, like the national science foundation,and again other players and collaborators. i showedyou my students and these are the collaboratorsprofessors at other universities and ucsb that i've worked at.

so thanks very much. come up afterwardsin and take a look. and ask more questions.

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